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What is the energy (E, in joules) of the 514.5 nm photons emitted by an argon-ion laser?


A) 4.29 * 10-36 J
B) 2.33 * 1035 J
C) 4.29 * 10-45 J
D) 3.86 * 10-19 J
E) 3.86 * 10-28 J

F) A) and E)
G) B) and D)

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Which statement below regarding the Bohr model of the atom is FALSE?


A) Changes in the energy of the atom involve the electron transitioning between allowed orbits.
B) The atom has discrete energy levels described by a quantum number n.
C) The electron does not radiate energy and spiral into the nucleus if it is in an allowed orbit.
D) The atom has zero energy when in its ground state.
E) The energy of an orbit is inversely proportional to N2.

F) C) and E)
G) A) and C)

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How many electrons in an atom can have quantum numbers n = 4, l l = 1?


A) 1
B) 2
C) 6
D) 4
E) 10

F) None of the above
G) A) and E)

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Which of the following occurs only in discrete (quantized) increments?


A) the speed a car drives on the interstate
B) the altitude at which an airplane flies
C) time
D) the level of water in a sink
E) money

F) A) and D)
G) B) and C)

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Which of the following objects, all moving at the same speed, will have the longest de Broglie wavelength?


A) a proton
B) an electron
C) a baseball
D) a neon atom
E) a neutron

F) B) and C)
G) A) and E)

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The atomic radius of germanium (Z = 32) is smaller than the atomic radius of potassium (Z = 19) because of _______.


A) a change in the n quantum number.
B) an increase in the effective nuclear charge.
C) the fact that p and d orbitals have the same orbital penetration.
D) a decrease in the effective nuclear charge.
E) germanium having 32 rather than 19 electrons.

F) B) and C)
G) B) and E)

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Which of the following is the ground-state electron configuration of the Ca2+ ion?


A) [Ar]4s23d2
B) [Ar]4s2
C) [Ar]4s24p2
D) [Ne]3s23p6
E) [Ne]3s23p8

F) B) and E)
G) A) and D)

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What is the kinetic energy of the photoelectrons emitted from a sodium surface ( Φ\varPhi = 2.9 * 10-19 J) when it is irradiated by photons with a wavelength of 350 nm?


A) 2.9 *10-19 J
B) 5.7 * 10-19 J
C) 0 J
D) 2.8 * 10-19 J
E) 3.6 * 10-19 J

F) D) and E)
G) B) and D)

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How many times longer is the de Broglie wavelength of a helium atom (6.647 *10-27 kg) moving at 220 m/s than that of a baseball (0.145 kg) moving at 35 m/s?


A) 3.5 *1024
B) 2.2 *1025
C) 9.5 * 1033
D) 1.5 * 109
E) 3.7 * 1034

F) C) and D)
G) None of the above

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How many orbitals are possible for the n = 3 shell?


A) 1
B) 2
C) 3
D) 6
E) 9

F) A) and C)
G) All of the above

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Which set of quantum numbers below is allowed?


A) n = 2, l l = 2, ml = 0, ms = - ½
B) n = 7, l l = 0, ml = 0, ms = + ½
C) n = 7, l l = -1, ml = -1, ms = - ½
D) n = 1, l l = 2, ml = 0, ms = +½
E) n = 5, l l = 6, ml = -2, ms = - ½

F) All of the above
G) B) and E)

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B

Which of the following is NOT an allowed value for the principal quantum number?


A) 1
B) 3
C) 10
D) 0
E) 2

F) A) and E)
G) B) and C)

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Indicate which of the following photons can cause the emission of photoelectrons from a surface of gallium ( Φ\varPhi = 6.7 * 10-19 J) .


A) 350 nm
B) 400 nm
C) 200 nm
D) 650 nm
E) 500 nm

F) None of the above
G) A) and B)

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C

Transition metal ions typically lose their outermost ns electrons before losing any (n - 1) d electrons.What is the best explanation of this frequently observed trend?


A) The ns electrons have lower angular momentum.
B) The (n - 1) d electrons have a larger average radius.
C) The (n - 1) d orbitals can have more electrons with unpaired spins.
D) The (n - 1) s and (n - 1) p subshells are full.
E) The (n - 1) d electrons experience a higher Zeff than the ns electrons.

F) None of the above
G) B) and E)

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Consider the radial distribution shown below for an electron in an s atomic orbital where r is the distance of the electron from the nucleus. Consider the radial distribution shown below for an electron in an s atomic orbital where r is the distance of the electron from the nucleus.   Identify:  1) where the atomic nucleus is located,  2) a radial node,  3) the most probable distance of the electron from the nucleus, and  4) the principal quantum number for this orbital. Identify: 1) where the atomic nucleus is located, 2) a radial node, 3) the most probable distance of the electron from the nucleus, and 4) the principal quantum number for this orbital.

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1) The nucleus is located at A...

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What is the shortest wavelength of light emitted by an excited hydrogen atom when nfinal = 3?


A) 91.16 nm
B) 121.5 nm
C) 273.5 nm
D) 821.4 nm
E) 1875.8 nm

F) A) and B)
G) D) and E)

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Sodium lamps emit yellow light with a nominal wavelength of 589 nm.What is the energy of these photons in kilojoules per mole?


A) 3.37 * 10-9 kJ/mol
B) 2.35 * 10-7 kJ/mol
C) 120 kJ/mol
D) 70.5 kJ/mol
E) 203 kJ/mol

F) A) and E)
G) D) and E)

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E

An electron moving at _______ will have the smallest de Broglie wavelength.


A) 220 m/s
B) 20 mph
C) 3600 km/s
D) 25% of the speed of light
E) 2.998 *108 km/hr

F) A) and B)
G) A) and C)

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Which transition in a hydrogen atom will cause emission of the shortest wavelength photon?


A) ninitial = 5 to nfinal = 3
B) ninitial = 4 to nfinal = 3
C) ninitial = 4 to nfinal = 2
D) ninitial = 3 to nfinal = 2
E) ninitial = 3 to nfinal = 1

F) B) and C)
G) None of the above

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The energy of a one-electron atom or ion is given by (2.178×1018 J) Z2n2 \left(-2.178 \times 10^{-18} \mathrm{~J}\right) \frac{Z^{2}}{n^{2}} where Z is the atomic number of the element.Which one-electron ion below would require the most energy to remove its electron?


A) Li2+
B) Be3+
C) He+
D) B4+
E) C5+

F) C) and D)
G) A) and E)

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